Stable Diazo Printing Colors and a New Explanation of the Constitution of Diazo Compounds

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A paper by Dr. W. Sieber, read at the Twelfth Congress of the International Society of Chemists and Colourists in Carlsbad, on stabilizing diazo printing colours used with beta-naphthol prepares on cotton. He reports that boric acid and tungstic acid can replace acetic acid, gives recipes for preparing the stable diazo colours from p-nitraniline, m-nitraniline or p-nitro-o-anisidine, and compares dissociation constants of the acids. The second half proposes a new explanation of the constitution of diazo compounds, arguing that nitrous acid first forms an addition (molecular) compound with the amine rather than a condensation product.

Type
Article
Date
1929
Language
English
Pages
5
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